專業從事離子液體的合成、應用及其相關技術的研究工作------中科院蘭州化學物理研究所納米催化組

• [Wiley數據庫][2011] Catalytic Conversion of Carbohydrates into 5-Hydroxymethylfurfural by Germanium(IV) Chloride in Ionic Liquids
• 更新時間：2016-01-20；信息類型：期刊文章
• Direct conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) catalyzed by germanium(IV) chloride in ionic liquids has been investigated in search of an efficient and environmentally friendly process. Monosaccharides d-fructose and d-glucose, disaccharides sucrose and maltose, and even the polysaccharide cellulose were successfully converted into HMF with good yields under mild conditions (yield up to 92% in 5 min in the case of fructose). The structure of ionic liquids,catalyst loading, reaction temperature and water content had noticeable effects on this catalytic system. Addition of 5 molecular sieves during the dehydration of glucose resulted in an increase in HMF yield from 38.4% to 48.4%. A mechanism for glucose conversion to HMF catalyzed by germanium(IV) chloride was proposed according to 13C NMR spectra obtained in situ under different conditions using d-glucose-2-13C as the substrate.
• 鏈接地址：http://www.abmbags.com/download/c-articles/2016-01-20/323.html

• [Wiley數據庫][2011]Catalytic Conversion of Carbohydrates into 5-Hydroxymethylfurfural by Germanium(IV)
• 更新時間：2016-01-20；信息類型：客戶發表SCI論文介紹
• 題名：Catalytic Conversion of Carbohydrates into 5-Hydroxymethylfurfural by Germanium(IV) Chloride in Ionic Liquids
• 鏈接地址：http://www.abmbags.com/research/2016-01-20/420.html

• Production of Nanocatalyst Applicable in Synthesis of Organic Compounds
• 更新時間：2015-02-16；信息類型：國外研究進展
• Iranian researchers succeeded in the production of a new nanocatalyst which eliminates the need for application of organic solvents in the synthesis of organic compounds.
• 鏈接地址：http://www.abmbags.com/research/2015-11-04/409.html

• 遼陽石化成功開發EC離子液體催化劑
• 更新時間：2015-02-07；信息類型：產業化
• 2月3日，記者從遼陽石化公司獲悉，經過兩年研制，這個公司成功開發的環氧乙烷和二氧化碳羰基化合成碳酸乙烯酯（EC）離子液體催化劑，在低 溫、低壓條件下轉化率達100%，選擇性達98%，具有活性高、穩定性好、原料適用性強、生產成本低等特點。
• 鏈接地址：http://www.abmbags.com/research/2015-11-02/369.html

• 環境友好的復合離子液體催化碳四烷基化新技術（CILA）取得重大突破
• 更新時間：2015-01-02；信息類型：產業化
• 碳四烷基化汽油具有高辛烷值、無硫、無烯、無芳等優點，是理想的汽油調和組分。傳統工藝以濃硫酸或氫氟酸為催化劑，存在嚴重的設備腐蝕及潛在的環境 污染與人身危害等重大問題，其工業應用受到了越來越大的挑戰。因此，環境友好的烷基化生產技術的開發一直是世界煉油工業的焦點。
• 鏈接地址：http://www.abmbags.com/research/2015-11-02/370.html

• Petronas unit gives Remcoat marketing rights to Wasco
• 更新時間：2014-12-30；信息類型：國外研究進展
• Wong said Remcoat was the second major proprietary product commercialised by Petronas this year after “HycaPure Hg”, a solid-supported ionic liquid mercury removal technology that it signed with Clariant in March this year.
• 鏈接地址：http://www.abmbags.com/research/2014-12-30/356.html

• Driving towards success with biomass-derived petrol
• 更新時間：2014-11-10；信息類型：國內研究進展
• Chinese scientists have overcome previous limitations to generate high octane number petrol from biomass-derived γ-valerolactone (GVL), an organic compound that is already often blended in small amounts with petrol or diesel. Using an ionic liquid catalyst, the conversion churned out a 2,2,4-trimethylpentane-rich substance with an octane number of 95.4, the highest reported for biomass derived fuel.
• 鏈接地址：http://www.abmbags.com/research/2015-11-04/407.html

• Catalytic Properties Developed in Newly-Produced Nanocomposite
• 更新時間：2014-07-07；信息類型：國外研究進展
• The biosensors made of this nanocomposite act as electrochemical sensors and are able to detect the amount of drugs.
• 鏈接地址：http://www.abmbags.com/research/2014-07-07/323.html

• 日本仙臺東北大學和新日鐵化學公司聯合開發的基于離子液體低溫己內酰胺合成工藝
• 更新時間：2014-04-18；信息類型：工業應用>成功案例
• 日本仙臺東北大學和新日鐵化學公司聯合開發出以超臨界CO2(約30℃、壓力超過8MPa) 作為抽提分離溶劑的低溫己內酰胺合成工藝。該工藝采用一種新開發的離子液體催化劑, 可使反應在接近室溫(約50℃) 的條件下進行, 反應中無需使用有機溶劑, 是一種綠色化學工藝, 而且不會產生硫銨等副產物。離子液體通常在室溫下是一種鹽類, 新工藝采用的是一種N-甲基咪唑鎓鹽。
• 鏈接地址：http://www.abmbags.com/application/2014-04-18/23.html

• 中國科學院蘭州化學物理研究所開發的基于離子液體的熱裂解制異氰酸酯工藝
• 更新時間：2014-04-14；信息類型：工業應用>成功案例
• 中國科學院蘭州化學物理研究所系統研究了以氨基甲酸酯和一氧化碳為羰源合成N-取代氨基甲酸酯并經熱裂解制異氰酸酯過程，形成多個優良的催化劑。通過共沉淀-焙燒-還原的方法發展出磁性四氧化三鐵負載納米鎳催化劑（Ni/Fe3O4），高效的實現了甲苯二胺、4,4'-二苯氨基甲烷二胺、異佛爾酮二胺等為原料制備相應的N-取代氨基甲酸酯。通過系統表征，揭示出納米態Fe-Ni 合金是可能的活性組分，同位素示蹤反應和機理研究發現N,N’-二取代脲是反應的中間體。
• 鏈接地址：http://www.abmbags.com/application/2014-04-14/13.html